One of the recent features of the vSphere Cluster Services (vCLS) is the ability configure the vSphere Datastores that vCLS is allowed to use to provision the required service VMs, which can be on a vSphere Cluster under Configure->vSphere Cluster Services->Datastores as shown in the screenshot below.
In addition to the vSphere UI, you can also programmatically update this configuration using the vSphere API and with tools like PowerCLI as one of the interfaces to the API.